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Chromatographic studies of n-Propyl Propionate: Adsorption equilibrium, modelling and uncertainties determination

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Chromatographic studies of n-Propyl Propionate : Adsorption equilibrium, modelling and uncertainties determination. / Nogueira, Idelfonso B.R.; Faria, Rui P.V.; Requião, Reiner; Koivisto, Hannu; Martins, Márcio A.F.; Rodrigues, Alírio E.; Loureiro, José M.; Ribeiro, Ana M.

In: Computers and Chemical Engineering, Vol. 119, 02.11.2018, p. 371-382.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Nogueira, IBR, Faria, RPV, Requião, R, Koivisto, H, Martins, MAF, Rodrigues, AE, Loureiro, JM & Ribeiro, AM 2018, 'Chromatographic studies of n-Propyl Propionate: Adsorption equilibrium, modelling and uncertainties determination', Computers and Chemical Engineering, vol. 119, pp. 371-382. https://doi.org/10.1016/j.compchemeng.2018.09.020

APA

Nogueira, I. B. R., Faria, R. P. V., Requião, R., Koivisto, H., Martins, M. A. F., Rodrigues, A. E., ... Ribeiro, A. M. (2018). Chromatographic studies of n-Propyl Propionate: Adsorption equilibrium, modelling and uncertainties determination. Computers and Chemical Engineering, 119, 371-382. https://doi.org/10.1016/j.compchemeng.2018.09.020

Vancouver

Nogueira IBR, Faria RPV, Requião R, Koivisto H, Martins MAF, Rodrigues AE et al. Chromatographic studies of n-Propyl Propionate: Adsorption equilibrium, modelling and uncertainties determination. Computers and Chemical Engineering. 2018 Nov 2;119:371-382. https://doi.org/10.1016/j.compchemeng.2018.09.020

Author

Nogueira, Idelfonso B.R. ; Faria, Rui P.V. ; Requião, Reiner ; Koivisto, Hannu ; Martins, Márcio A.F. ; Rodrigues, Alírio E. ; Loureiro, José M. ; Ribeiro, Ana M. / Chromatographic studies of n-Propyl Propionate : Adsorption equilibrium, modelling and uncertainties determination. In: Computers and Chemical Engineering. 2018 ; Vol. 119. pp. 371-382.

Bibtex - Download

@article{8a09052bc6fa4730858b9e2284e9c06e,
title = "Chromatographic studies of n-Propyl Propionate: Adsorption equilibrium, modelling and uncertainties determination",
abstract = "The n-Propyl Propionate (ProPro) is a compound that has several possible industrial applications. However, the current production route of this component presents several problems, such as the downstream purification. In this way, chromatographic separation could be an alternative solution to the downstream purification. In this work experimental studies of the ProPro reaction system separation in a chromatographic fixed bed unit packed with Amberlyst 46 were performed. The adsorption equilibrium isotherms and the corresponding Langmuir model parameters were determined. A phenomenological model to represent the process was developed and validated through the experimental data. Meanwhile, it is proposed the characterization of the uncertainties of all steps and its extension to the model prediction, which allowed to estimate the model parameters with a reduced number of experiments, when compared with other reports in the literature; nevertheless, the final results lead to a statistically more reliable model.",
keywords = "Adsorption equilibrium isotherms, Confidence region, Fixed bed adsorptive unit, n-Propyl Propionate, Particle swarm optimization",
author = "Nogueira, {Idelfonso B.R.} and Faria, {Rui P.V.} and Reiner Requi{\~a}o and Hannu Koivisto and Martins, {M{\'a}rcio A.F.} and Rodrigues, {Al{\'i}rio E.} and Loureiro, {Jos{\'e} M.} and Ribeiro, {Ana M.}",
year = "2018",
month = "11",
day = "2",
doi = "10.1016/j.compchemeng.2018.09.020",
language = "English",
volume = "119",
pages = "371--382",
journal = "Computers and Chemical Engineering",
issn = "0098-1354",
publisher = "Elsevier",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Chromatographic studies of n-Propyl Propionate

T2 - Adsorption equilibrium, modelling and uncertainties determination

AU - Nogueira, Idelfonso B.R.

AU - Faria, Rui P.V.

AU - Requião, Reiner

AU - Koivisto, Hannu

AU - Martins, Márcio A.F.

AU - Rodrigues, Alírio E.

AU - Loureiro, José M.

AU - Ribeiro, Ana M.

PY - 2018/11/2

Y1 - 2018/11/2

N2 - The n-Propyl Propionate (ProPro) is a compound that has several possible industrial applications. However, the current production route of this component presents several problems, such as the downstream purification. In this way, chromatographic separation could be an alternative solution to the downstream purification. In this work experimental studies of the ProPro reaction system separation in a chromatographic fixed bed unit packed with Amberlyst 46 were performed. The adsorption equilibrium isotherms and the corresponding Langmuir model parameters were determined. A phenomenological model to represent the process was developed and validated through the experimental data. Meanwhile, it is proposed the characterization of the uncertainties of all steps and its extension to the model prediction, which allowed to estimate the model parameters with a reduced number of experiments, when compared with other reports in the literature; nevertheless, the final results lead to a statistically more reliable model.

AB - The n-Propyl Propionate (ProPro) is a compound that has several possible industrial applications. However, the current production route of this component presents several problems, such as the downstream purification. In this way, chromatographic separation could be an alternative solution to the downstream purification. In this work experimental studies of the ProPro reaction system separation in a chromatographic fixed bed unit packed with Amberlyst 46 were performed. The adsorption equilibrium isotherms and the corresponding Langmuir model parameters were determined. A phenomenological model to represent the process was developed and validated through the experimental data. Meanwhile, it is proposed the characterization of the uncertainties of all steps and its extension to the model prediction, which allowed to estimate the model parameters with a reduced number of experiments, when compared with other reports in the literature; nevertheless, the final results lead to a statistically more reliable model.

KW - Adsorption equilibrium isotherms

KW - Confidence region

KW - Fixed bed adsorptive unit

KW - n-Propyl Propionate

KW - Particle swarm optimization

U2 - 10.1016/j.compchemeng.2018.09.020

DO - 10.1016/j.compchemeng.2018.09.020

M3 - Article

VL - 119

SP - 371

EP - 382

JO - Computers and Chemical Engineering

JF - Computers and Chemical Engineering

SN - 0098-1354

ER -