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Convenient extraction method for quantification of thin zinc patina layers

Research output: Contribution to journalArticleScientificpeer-review

Details

Original languageEnglish
Pages (from-to)564-570
JournalSurface and Interface Analysis
Volume50
Issue number5
Early online date1 Jan 2018
DOIs
Publication statusPublished - 2018
Publication typeA1 Journal article-refereed

Abstract

Synthetic zinc patina was grown on galvanized steel sheets in supercritical carbon dioxide atmosphere. Different patina compounds were dissolved and quantified using a stepwise immersion and dissolution procedure. The distinct patina components, namely anhydrous zinc carbonate (a dense layer adjacent to metallic zinc) and zinc hydroxy carbonate (nanowires on the surface), were dissolved in glycine solutions, followed by quantification of Zn2+ in the solutes by X-ray fluorescence. The zinc hydroxy carbonate nanowires were readily glycine soluble, and the anhydrous zinc carbonate showed scarce glycine solubility, which enabled their selective quantification. The amount of the remaining (anhydrous) zinc carbonate after glycine extraction was determined from the glycine-soluble zinc oxide after calcination (heat treatment for 10 minutes at 350°C). The results were verified by scanning electron microscopy imaging and Fourier transform infrared spectroscopy measurements.

Keywords

  • Galvanized steel, Glycine, Supercritical carbon dioxide, Zinc carbonate, Zinc nanowires, Zinc oxide

Publication forum classification

Field of science, Statistics Finland