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Coordination networks incorporating halogen-bond donor sites and azobenzene groups

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Coordination networks incorporating halogen-bond donor sites and azobenzene groups. / Fernandez-Palacio, Francisco; Saccone, Marco; Priimägi, Arri; Terraneo, Giancarlo; Pilati, Tullio; Metrangolo, Pierangelo; Resnati, Giuseppe.

In: CrystEngComm, Vol. 18, No. 13, 07.04.2016, p. 2251-2257.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Fernandez-Palacio, F, Saccone, M, Priimägi, A, Terraneo, G, Pilati, T, Metrangolo, P & Resnati, G 2016, 'Coordination networks incorporating halogen-bond donor sites and azobenzene groups', CrystEngComm, vol. 18, no. 13, pp. 2251-2257. https://doi.org/10.1039/c6ce00059b

APA

Fernandez-Palacio, F., Saccone, M., Priimägi, A., Terraneo, G., Pilati, T., Metrangolo, P., & Resnati, G. (2016). Coordination networks incorporating halogen-bond donor sites and azobenzene groups. CrystEngComm, 18(13), 2251-2257. https://doi.org/10.1039/c6ce00059b

Vancouver

Fernandez-Palacio F, Saccone M, Priimägi A, Terraneo G, Pilati T, Metrangolo P et al. Coordination networks incorporating halogen-bond donor sites and azobenzene groups. CrystEngComm. 2016 Apr 7;18(13):2251-2257. https://doi.org/10.1039/c6ce00059b

Author

Fernandez-Palacio, Francisco ; Saccone, Marco ; Priimägi, Arri ; Terraneo, Giancarlo ; Pilati, Tullio ; Metrangolo, Pierangelo ; Resnati, Giuseppe. / Coordination networks incorporating halogen-bond donor sites and azobenzene groups. In: CrystEngComm. 2016 ; Vol. 18, No. 13. pp. 2251-2257.

Bibtex - Download

@article{4f0bbe187d70472c85ecdf2c1a6c6446,
title = "Coordination networks incorporating halogen-bond donor sites and azobenzene groups",
abstract = "Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.",
author = "Francisco Fernandez-Palacio and Marco Saccone and Arri Priim{\"a}gi and Giancarlo Terraneo and Tullio Pilati and Pierangelo Metrangolo and Giuseppe Resnati",
year = "2016",
month = "4",
day = "7",
doi = "10.1039/c6ce00059b",
language = "English",
volume = "18",
pages = "2251--2257",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "13",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Coordination networks incorporating halogen-bond donor sites and azobenzene groups

AU - Fernandez-Palacio, Francisco

AU - Saccone, Marco

AU - Priimägi, Arri

AU - Terraneo, Giancarlo

AU - Pilati, Tullio

AU - Metrangolo, Pierangelo

AU - Resnati, Giuseppe

PY - 2016/4/7

Y1 - 2016/4/7

N2 - Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.

AB - Two Zn coordination networks, {[Zn(1)(Py)2]2(2-propanol)}n (3) and {[Zn(1)2(Bipy)2](DMF)2}n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized. Obtaining 3 and 4 confirms that it is possible to use a ligand wherein its coordination bond acceptor sites and XB donor sites are on the same molecular scaffold (i.e., an aromatic ring) without interfering with each other. We demonstrate that XBs play a fundamental role in the architectures and properties of the obtained coordination networks. In 3, XBs promote the formation of 2D supramolecular layers, which, by overlapping each other, allow the incorporation of 2-propanol as a guest molecule. In 4, XBs support the connection of the layers and are essential to firmly pin DMF solvent molecules through I⋯O contacts, thus increasing the stability of the solvated systems.

U2 - 10.1039/c6ce00059b

DO - 10.1039/c6ce00059b

M3 - Article

VL - 18

SP - 2251

EP - 2257

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 13

ER -