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Formation and stability of carbon nanotube network in natural rubber: Effect of non-rubber components

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Formation and stability of carbon nanotube network in natural rubber : Effect of non-rubber components. / Le, H. H.; Pham, T.; Henning, S.; Klehm, J.; Wießner, S.; Stöckelhuber, K. W.; Das, A.; Hoang, X. T.; Do, Q. K.; Wu, M.; Vennemann, N.; Heinrich, G.; Radusch, H. J.

In: Polymer, Vol. 73, 18004, 05.08.2015, p. 111-121.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Le, HH, Pham, T, Henning, S, Klehm, J, Wießner, S, Stöckelhuber, KW, Das, A, Hoang, XT, Do, QK, Wu, M, Vennemann, N, Heinrich, G & Radusch, HJ 2015, 'Formation and stability of carbon nanotube network in natural rubber: Effect of non-rubber components', Polymer, vol. 73, 18004, pp. 111-121. https://doi.org/10.1016/j.polymer.2015.07.044

APA

Le, H. H., Pham, T., Henning, S., Klehm, J., Wießner, S., Stöckelhuber, K. W., ... Radusch, H. J. (2015). Formation and stability of carbon nanotube network in natural rubber: Effect of non-rubber components. Polymer, 73, 111-121. [18004]. https://doi.org/10.1016/j.polymer.2015.07.044

Vancouver

Le HH, Pham T, Henning S, Klehm J, Wießner S, Stöckelhuber KW et al. Formation and stability of carbon nanotube network in natural rubber: Effect of non-rubber components. Polymer. 2015 Aug 5;73:111-121. 18004. https://doi.org/10.1016/j.polymer.2015.07.044

Author

Le, H. H. ; Pham, T. ; Henning, S. ; Klehm, J. ; Wießner, S. ; Stöckelhuber, K. W. ; Das, A. ; Hoang, X. T. ; Do, Q. K. ; Wu, M. ; Vennemann, N. ; Heinrich, G. ; Radusch, H. J. / Formation and stability of carbon nanotube network in natural rubber : Effect of non-rubber components. In: Polymer. 2015 ; Vol. 73. pp. 111-121.

Bibtex - Download

@article{44d7df32a2794523b38ef8592b092c24,
title = "Formation and stability of carbon nanotube network in natural rubber: Effect of non-rubber components",
abstract = "Abstract The formation and stability of carbon nanotube (CNT) network in natural rubber (NR), deproteinized NR (DPNR) and polyisoprene (IR) compound were investigated by means of the method of the online measured electrical conductance in a whole process from processing and rolling over pressing/cross-linking to post-stretching. The kinetics of CNT flocculation was described and explained by taking into consideration the depletion force considered as driving force and the thickness of the bound rubber layer considered as hindering factor. The presence of linked phospholipids in NR and DPNR improves the rubber-filler interaction of CNTs through the cation-π bonding that hinders the filler flocculation. The absence of the cation-π bonding in CNT/IR compound and the related thin layer of bound rubber are the reason for the strong tendency of flocculation of CNTs in IR even at room temperature. The effect of pressing time, temperature and cross-linking reaction as well as mechanical deformation on the formation and stability of CNT network in NR compounds was also investigated and discussed by taking into consideration the role of the linked phospholipids.",
keywords = "Carbon nanotubes, Electrical conductivity, Filler network, Nanocomposites, Rubber",
author = "Le, {H. H.} and T. Pham and S. Henning and J. Klehm and S. Wie{\ss}ner and St{\"o}ckelhuber, {K. W.} and A. Das and Hoang, {X. T.} and Do, {Q. K.} and M. Wu and N. Vennemann and G. Heinrich and Radusch, {H. J.}",
year = "2015",
month = "8",
day = "5",
doi = "10.1016/j.polymer.2015.07.044",
language = "English",
volume = "73",
pages = "111--121",
journal = "Polymer",
issn = "0032-3861",
publisher = "ELSEVIER SCI LTD",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Formation and stability of carbon nanotube network in natural rubber

T2 - Effect of non-rubber components

AU - Le, H. H.

AU - Pham, T.

AU - Henning, S.

AU - Klehm, J.

AU - Wießner, S.

AU - Stöckelhuber, K. W.

AU - Das, A.

AU - Hoang, X. T.

AU - Do, Q. K.

AU - Wu, M.

AU - Vennemann, N.

AU - Heinrich, G.

AU - Radusch, H. J.

PY - 2015/8/5

Y1 - 2015/8/5

N2 - Abstract The formation and stability of carbon nanotube (CNT) network in natural rubber (NR), deproteinized NR (DPNR) and polyisoprene (IR) compound were investigated by means of the method of the online measured electrical conductance in a whole process from processing and rolling over pressing/cross-linking to post-stretching. The kinetics of CNT flocculation was described and explained by taking into consideration the depletion force considered as driving force and the thickness of the bound rubber layer considered as hindering factor. The presence of linked phospholipids in NR and DPNR improves the rubber-filler interaction of CNTs through the cation-π bonding that hinders the filler flocculation. The absence of the cation-π bonding in CNT/IR compound and the related thin layer of bound rubber are the reason for the strong tendency of flocculation of CNTs in IR even at room temperature. The effect of pressing time, temperature and cross-linking reaction as well as mechanical deformation on the formation and stability of CNT network in NR compounds was also investigated and discussed by taking into consideration the role of the linked phospholipids.

AB - Abstract The formation and stability of carbon nanotube (CNT) network in natural rubber (NR), deproteinized NR (DPNR) and polyisoprene (IR) compound were investigated by means of the method of the online measured electrical conductance in a whole process from processing and rolling over pressing/cross-linking to post-stretching. The kinetics of CNT flocculation was described and explained by taking into consideration the depletion force considered as driving force and the thickness of the bound rubber layer considered as hindering factor. The presence of linked phospholipids in NR and DPNR improves the rubber-filler interaction of CNTs through the cation-π bonding that hinders the filler flocculation. The absence of the cation-π bonding in CNT/IR compound and the related thin layer of bound rubber are the reason for the strong tendency of flocculation of CNTs in IR even at room temperature. The effect of pressing time, temperature and cross-linking reaction as well as mechanical deformation on the formation and stability of CNT network in NR compounds was also investigated and discussed by taking into consideration the role of the linked phospholipids.

KW - Carbon nanotubes

KW - Electrical conductivity

KW - Filler network

KW - Nanocomposites

KW - Rubber

UR - http://www.scopus.com/inward/record.url?scp=84938566176&partnerID=8YFLogxK

U2 - 10.1016/j.polymer.2015.07.044

DO - 10.1016/j.polymer.2015.07.044

M3 - Article

VL - 73

SP - 111

EP - 121

JO - Polymer

JF - Polymer

SN - 0032-3861

M1 - 18004

ER -