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Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions

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Details

Original languageEnglish
Pages (from-to)746-749
Number of pages4
JournalNew Journal of Chemistry
Volume39
Issue number1
DOIs
Publication statusPublished - 1 Jan 2015
Publication typeA1 Journal article-refereed

Abstract

Addition of anions to perfluorinated 1,1′-biphenyl 1 or naphthalene 2 results in a shift of the 19F NMR signals. However, any specific interaction cannot be assigned to this effect. In order to study the interaction in more detail, the salt derivatives 3 and 4 were prepared and studied by single crystal X-ray diffraction revealing weak anion-π interactions in the solid state.

Publication forum classification

Field of science, Statistics Finland