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Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen-Bonded Anions

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Details

Original languageEnglish
Pages (from-to)6300-6304
JournalAngewandte Chemie (International Edition)
Volume55
Issue number21
DOIs
Publication statusPublished - 2016
Publication typeA1 Journal article-refereed

Abstract

Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen-bonded supramolecular anions [CnF2n+1-I···I···I-CnF2n+1]- are reported. The material system is unique in many ways, demonstrating for the first time 1)ionic, halogen-bonded liquid crystals, and 2)imidazolium-based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation.

ASJC Scopus subject areas

Keywords

  • Fluorophobic effect, Halogen bonding, Ionic liquid crystals, Self-assembly, Supramolecular chemistry

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Field of science, Statistics Finland

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