Superfluorinated Ionic Liquid Crystals Based on Supramolecular, Halogen-Bonded Anions
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Details
| Original language | English |
|---|---|
| Pages (from-to) | 6300-6304 |
| Journal | Angewandte Chemie (International Edition) |
| Volume | 55 |
| Issue number | 21 |
| DOIs | |
| Publication status | Published - 2016 |
| Publication type | A1 Journal article-refereed |
Abstract
Unconventional ionic liquid crystals in which the liquid crystallinity is enabled by halogen-bonded supramolecular anions [CnF2n+1-I···I···I-CnF2n+1]- are reported. The material system is unique in many ways, demonstrating for the first time 1)ionic, halogen-bonded liquid crystals, and 2)imidazolium-based ionic liquid crystals in which the occurrence of liquid crystallinity is not driven by the alkyl chains of the cation.
ASJC Scopus subject areas
Keywords
- Fluorophobic effect, Halogen bonding, Ionic liquid crystals, Self-assembly, Supramolecular chemistry
Publication forum classification
Field of science, Statistics Finland
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