Tampere University of Technology

TUTCRIS Research Portal

Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes

Research output: Contribution to journalArticleScientificpeer-review

Standard

Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes. / Koskela, Jenni E.; Vapaavuori, Jaana; Hautala, Juho; Priimagi, Arri; Faul, Charl F J; Kaivola, Matti; Ras, Robin H A.

In: Journal of Physical Chemistry C, Vol. 116, No. 3, 26.01.2012, p. 2363-2370.

Research output: Contribution to journalArticleScientificpeer-review

Harvard

Koskela, JE, Vapaavuori, J, Hautala, J, Priimagi, A, Faul, CFJ, Kaivola, M & Ras, RHA 2012, 'Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes', Journal of Physical Chemistry C, vol. 116, no. 3, pp. 2363-2370. https://doi.org/10.1021/jp210706n

APA

Koskela, J. E., Vapaavuori, J., Hautala, J., Priimagi, A., Faul, C. F. J., Kaivola, M., & Ras, R. H. A. (2012). Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes. Journal of Physical Chemistry C, 116(3), 2363-2370. https://doi.org/10.1021/jp210706n

Vancouver

Koskela JE, Vapaavuori J, Hautala J, Priimagi A, Faul CFJ, Kaivola M et al. Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes. Journal of Physical Chemistry C. 2012 Jan 26;116(3):2363-2370. https://doi.org/10.1021/jp210706n

Author

Koskela, Jenni E. ; Vapaavuori, Jaana ; Hautala, Juho ; Priimagi, Arri ; Faul, Charl F J ; Kaivola, Matti ; Ras, Robin H A. / Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes. In: Journal of Physical Chemistry C. 2012 ; Vol. 116, No. 3. pp. 2363-2370.

Bibtex - Download

@article{1a02707e159a4d8485888f447a448f58,
title = "Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes",
abstract = "We report on phenol-pyridine hydrogen-bonded supramolecular polymer-azobenzene complexes made from a newly designed polar bisazobenzene chromophore. Because of the substitution with a polar nitro group, the chromophore possesses an extremely broad absorption band, spanning from near-UV up to 650 nm. Moreover, the inclusion of two methoxy groups to the central benzene ring prevents excessive chromophore-chromophore intermolecular interactions and provides advantageous size-related properties. Together, these features of the prepared photoresponsive polymer materials enable efficient inscription of (i) photoinduced birefringence with outstanding stability at various chromophore concentrations and (ii) surface-relief grating formation over a wide range of writing wavelengths from 405 to 633 nm. The photoresponsive behavior is compared to that of Disperse Yellow 7-based supramolecular complexes.",
author = "Koskela, {Jenni E.} and Jaana Vapaavuori and Juho Hautala and Arri Priimagi and Faul, {Charl F J} and Matti Kaivola and Ras, {Robin H A}",
year = "2012",
month = "1",
day = "26",
doi = "10.1021/jp210706n",
language = "English",
volume = "116",
pages = "2363--2370",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society ACS",
number = "3",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Surface-relief gratings and stable birefringence inscribed using light of broad spectral range in supramolecular polymer-bisazobenzene complexes

AU - Koskela, Jenni E.

AU - Vapaavuori, Jaana

AU - Hautala, Juho

AU - Priimagi, Arri

AU - Faul, Charl F J

AU - Kaivola, Matti

AU - Ras, Robin H A

PY - 2012/1/26

Y1 - 2012/1/26

N2 - We report on phenol-pyridine hydrogen-bonded supramolecular polymer-azobenzene complexes made from a newly designed polar bisazobenzene chromophore. Because of the substitution with a polar nitro group, the chromophore possesses an extremely broad absorption band, spanning from near-UV up to 650 nm. Moreover, the inclusion of two methoxy groups to the central benzene ring prevents excessive chromophore-chromophore intermolecular interactions and provides advantageous size-related properties. Together, these features of the prepared photoresponsive polymer materials enable efficient inscription of (i) photoinduced birefringence with outstanding stability at various chromophore concentrations and (ii) surface-relief grating formation over a wide range of writing wavelengths from 405 to 633 nm. The photoresponsive behavior is compared to that of Disperse Yellow 7-based supramolecular complexes.

AB - We report on phenol-pyridine hydrogen-bonded supramolecular polymer-azobenzene complexes made from a newly designed polar bisazobenzene chromophore. Because of the substitution with a polar nitro group, the chromophore possesses an extremely broad absorption band, spanning from near-UV up to 650 nm. Moreover, the inclusion of two methoxy groups to the central benzene ring prevents excessive chromophore-chromophore intermolecular interactions and provides advantageous size-related properties. Together, these features of the prepared photoresponsive polymer materials enable efficient inscription of (i) photoinduced birefringence with outstanding stability at various chromophore concentrations and (ii) surface-relief grating formation over a wide range of writing wavelengths from 405 to 633 nm. The photoresponsive behavior is compared to that of Disperse Yellow 7-based supramolecular complexes.

UR - http://www.scopus.com/inward/record.url?scp=84856360260&partnerID=8YFLogxK

U2 - 10.1021/jp210706n

DO - 10.1021/jp210706n

M3 - Article

VL - 116

SP - 2363

EP - 2370

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 3

ER -