Tampere University of Technology

TUTCRIS Research Portal

Vacancy-type defect distributions near argon sputtered Al(100) surface studied by variable-energy positrons and molecular dynamics simulations

Research output: Contribution to journalArticleScientificpeer-review

Details

Original languageEnglish
Pages (from-to)385-414
Number of pages30
JournalSurface Science
Volume175
Issue number2
DOIs
Publication statusPublished - 2 Sep 1986
Publication typeNot Eligible

Abstract

A beam of variable-energy positrons, whose back-diffusion probability is measured as a function of positron implantation energy, is applied to studies of depth distribution of sputtering damage in aluminum. The defects are produced by argon ion bombardment of an Al(110) surface in ultra-high vacuum. We have varied the Ar+ energy, incident angle and dose, as well as sputtering and annealing temperatures. The extracted defect profiles have typically a narrow peak at the surface with a width of 10-20 A and a broader tail extending down to 50-100 Å. The shape of the defect profile varies only slightly with the sputtering energy and angle. Defect production at less than 1 keV Ar+ energies is typically 1-5 vacancies per incident ion. The defect profiles become fluence-independent at about 2 × 1016 Ar+ cm-2. The defect density at the outer atomic layers saturates at high argon fluences to a few at%, depending on sputtering conditions. The sputtering temperature (below or above the vacancy migration stage at 250 K) has little effect on vacancy profiles. Defects anneal out gradually between 100 °C and 400 °C. Sputtering damage was also evaluated with the molecular dynamics technique. The shape and depth scale of the simulated collision cascades are in agreement with the experimentally extracted quantities.