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Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate)

Tutkimustuotosvertaisarvioitu

Standard

Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate). / Lesot, Philippe; Merlet, Denis; Courtieu, Jacques; Emsley, James W.; Rantala, Tapio T.; Jokisaari, Jukka.

julkaisussa: Journal of Physical Chemistry A, Vuosikerta 101, Nro 31, 31.07.1997, s. 5719-5724.

Tutkimustuotosvertaisarvioitu

Harvard

Lesot, P, Merlet, D, Courtieu, J, Emsley, JW, Rantala, TT & Jokisaari, J 1997, 'Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate)', Journal of Physical Chemistry A, Vuosikerta. 101, Nro 31, Sivut 5719-5724. https://doi.org/10.1021/jp9709262

APA

Lesot, P., Merlet, D., Courtieu, J., Emsley, J. W., Rantala, T. T., & Jokisaari, J. (1997). Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate). Journal of Physical Chemistry A, 101(31), 5719-5724. https://doi.org/10.1021/jp9709262

Vancouver

Lesot P, Merlet D, Courtieu J, Emsley JW, Rantala TT, Jokisaari J. Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate). Journal of Physical Chemistry A. 1997 heinä 31;101(31):5719-5724. https://doi.org/10.1021/jp9709262

Author

Lesot, Philippe ; Merlet, Denis ; Courtieu, Jacques ; Emsley, James W. ; Rantala, Tapio T. ; Jokisaari, Jukka. / Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate). Julkaisussa: Journal of Physical Chemistry A. 1997 ; Vuosikerta 101, Nro 31. Sivut 5719-5724.

Bibtex - Lataa

@article{21f6de98195d4af09399757f8f8e169a,
title = "Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate)",
abstract = "The proton and natural abundance carbon-13 NMR spectra of (±)-3-butyn-2-ol enriched in the S enantiomer (ee = 72{\%}) and oriented in the chiral nematic liquid crystalline phase of [poly(γ-benzyl-L-glutamate)/ deuterochloroform] have been obtained and analyzed. The residual 1H-1H and 1H-13C dipolar couplings were corrected for the effects of molecular harmonic vibrational motions and used to determine the ra structure and the five independent order parameters, Sαβ, for each enantiomer. It is shown that the data is consistent with the two enantiomers having an identical rα, structure, but the order matrices differ in both the magnitudes of their elements and the orientation of their principal axes.",
author = "Philippe Lesot and Denis Merlet and Jacques Courtieu and Emsley, {James W.} and Rantala, {Tapio T.} and Jukka Jokisaari",
year = "1997",
month = "7",
day = "31",
doi = "10.1021/jp9709262",
language = "English",
volume = "101",
pages = "5719--5724",
journal = "Journal of Physical Chemistry A",
issn = "1089-5639",
publisher = "American Chemical Society",
number = "31",

}

RIS (suitable for import to EndNote) - Lataa

TY - JOUR

T1 - Calculation of the molecular ordering parameters of (±)-3-butyn-2-ol dissolved in an organic solution of poly(γ-benzyl-L-glutamate)

AU - Lesot, Philippe

AU - Merlet, Denis

AU - Courtieu, Jacques

AU - Emsley, James W.

AU - Rantala, Tapio T.

AU - Jokisaari, Jukka

PY - 1997/7/31

Y1 - 1997/7/31

N2 - The proton and natural abundance carbon-13 NMR spectra of (±)-3-butyn-2-ol enriched in the S enantiomer (ee = 72%) and oriented in the chiral nematic liquid crystalline phase of [poly(γ-benzyl-L-glutamate)/ deuterochloroform] have been obtained and analyzed. The residual 1H-1H and 1H-13C dipolar couplings were corrected for the effects of molecular harmonic vibrational motions and used to determine the ra structure and the five independent order parameters, Sαβ, for each enantiomer. It is shown that the data is consistent with the two enantiomers having an identical rα, structure, but the order matrices differ in both the magnitudes of their elements and the orientation of their principal axes.

AB - The proton and natural abundance carbon-13 NMR spectra of (±)-3-butyn-2-ol enriched in the S enantiomer (ee = 72%) and oriented in the chiral nematic liquid crystalline phase of [poly(γ-benzyl-L-glutamate)/ deuterochloroform] have been obtained and analyzed. The residual 1H-1H and 1H-13C dipolar couplings were corrected for the effects of molecular harmonic vibrational motions and used to determine the ra structure and the five independent order parameters, Sαβ, for each enantiomer. It is shown that the data is consistent with the two enantiomers having an identical rα, structure, but the order matrices differ in both the magnitudes of their elements and the orientation of their principal axes.

UR - http://www.scopus.com/inward/record.url?scp=0031175387&partnerID=8YFLogxK

U2 - 10.1021/jp9709262

DO - 10.1021/jp9709262

M3 - Article

VL - 101

SP - 5719

EP - 5724

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

SN - 1089-5639

IS - 31

ER -