Chlorine induced high temperature corrosion resistance of Cr3C2-based HVOF and HVAF thermally sprayed coatings
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Chlorine induced high temperature corrosion resistance of Cr3C2-based HVOF and HVAF thermally sprayed coatings. / Fantozzi, Davide; Matikainen, Ville ; Uusitalo, Mikko; Koivuluoto, Heli ; Vuoristo, Petri .
julkaisussa: Corrosion Science, Vuosikerta 160, 108166, 2019.Tutkimustuotos › › vertaisarvioitu
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TY - JOUR
T1 - Chlorine induced high temperature corrosion resistance of Cr3C2-based HVOF and HVAF thermally sprayed coatings
AU - Fantozzi, Davide
AU - Matikainen, Ville
AU - Uusitalo, Mikko
AU - Koivuluoto, Heli
AU - Vuoristo, Petri
PY - 2019
Y1 - 2019
N2 - A novel method that combines thermal analysis and traditional furnace corrosion tests was used to study the corrosion behaviour of thermally sprayed Cr3C2-based hardmetal coatings at 450 °C and 550 °C under a KCl deposit. This method enabled the identification of the onset temperature of chlorine-induced oxidation to be within 450–500 °C. Two corrosion mechanisms were suggested for these temperatures. At 450 °C, the corrosion rate was slow and mainly controlled by the formation of K2CrO4. Exposure at 550 °C caused the formation of fine interconnected secondary-carbide precipitates in the metal matrix. Their fast corrosion was identified as the major cause of degradation.
AB - A novel method that combines thermal analysis and traditional furnace corrosion tests was used to study the corrosion behaviour of thermally sprayed Cr3C2-based hardmetal coatings at 450 °C and 550 °C under a KCl deposit. This method enabled the identification of the onset temperature of chlorine-induced oxidation to be within 450–500 °C. Two corrosion mechanisms were suggested for these temperatures. At 450 °C, the corrosion rate was slow and mainly controlled by the formation of K2CrO4. Exposure at 550 °C caused the formation of fine interconnected secondary-carbide precipitates in the metal matrix. Their fast corrosion was identified as the major cause of degradation.
U2 - 10.1016/j.corsci.2019.108166
DO - 10.1016/j.corsci.2019.108166
M3 - Article
VL - 160
JO - Corrosion Science
JF - Corrosion Science
SN - 0010-938X
M1 - 108166
ER -