Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation
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Yksityiskohdat
Alkuperäiskieli | Englanti |
---|---|
Sivut | 7806-7810 |
Sivumäärä | 5 |
Julkaisu | Angewandte Chemie (International Edition) |
Vuosikerta | 55 |
Numero | 27 |
DOI - pysyväislinkit | |
Tila | Julkaistu - 2016 |
Julkaistu ulkoisesti | Kyllä |
OKM-julkaisutyyppi | A1 Alkuperäisartikkeli |
Tiivistelmä
Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.