Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation
Tutkimustuotos › › vertaisarvioitu
Yksityiskohdat
| Alkuperäiskieli | Englanti |
|---|---|
| Sivut | 7806-7810 |
| Sivumäärä | 5 |
| Julkaisu | Angewandte Chemie (International Edition) |
| Vuosikerta | 55 |
| Numero | 27 |
| DOI - pysyväislinkit | |
| Tila | Julkaistu - 2016 |
| Julkaistu ulkoisesti | Kyllä |
| OKM-julkaisutyyppi | A1 Alkuperäisartikkeli |
Tiivistelmä
Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.