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Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer

Tutkimustuotosvertaisarvioitu

Standard

Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer. / Basu, Debdipta; Das, Amit; Wang, De Yi; George, Jinu Jacob; Stöckelhuber, Klaus Werner; Boldt, Regine; Leuteritz, Andreas; Heinrich, Gert.

julkaisussa: RSC Advances, Vuosikerta 6, Nro 31, 2016, s. 26425-26436.

Tutkimustuotosvertaisarvioitu

Harvard

Basu, D, Das, A, Wang, DY, George, JJ, Stöckelhuber, KW, Boldt, R, Leuteritz, A & Heinrich, G 2016, 'Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer', RSC Advances, Vuosikerta. 6, Nro 31, Sivut 26425-26436. https://doi.org/10.1039/c5ra27444c

APA

Basu, D., Das, A., Wang, D. Y., George, J. J., Stöckelhuber, K. W., Boldt, R., ... Heinrich, G. (2016). Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer. RSC Advances, 6(31), 26425-26436. https://doi.org/10.1039/c5ra27444c

Vancouver

Basu D, Das A, Wang DY, George JJ, Stöckelhuber KW, Boldt R et al. Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer. RSC Advances. 2016;6(31):26425-26436. https://doi.org/10.1039/c5ra27444c

Author

Basu, Debdipta ; Das, Amit ; Wang, De Yi ; George, Jinu Jacob ; Stöckelhuber, Klaus Werner ; Boldt, Regine ; Leuteritz, Andreas ; Heinrich, Gert. / Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer. Julkaisussa: RSC Advances. 2016 ; Vuosikerta 6, Nro 31. Sivut 26425-26436.

Bibtex - Lataa

@article{bff2d404bf0447ce83dbaf18cb365189,
title = "Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer",
abstract = "In this work we describe layered double hydroxide (LDH), known as naturally occurring hydrotalcite, based rubber composites that can serve as outstanding fire retardant elastomeric materials. The preparation and detailed characterization of these composites are presented in this study. The inherent slow sulfur cure nature of EPDM rubber is considerably improved by the addition of LDH as realised by the observation of a shortening of the vulcanization time and an improvement of ultimate rheometric torque. This behavior of LDH signifies not only the filler-like character of itself, but also offers vulcanization active surface properties of layered double hydroxide particles. A good rubber-filler interaction was also realised by observing a positive shift of the glass transition temperature of ethylene propylene diene rubber (EPDM) in dynamic mechanical analysis (DMA). The flame retardant property was studied by the cone calorimeter test. The cone calorimeter investigation with sulfur cured gum rubber compounds found a peak heat release rate (PHRR) value of 654 kW m-2. However, at a higher phr loading of Zn-Al LDH i.e., at 40 phr and 100 phr, the PHRR is diminished to 311 kW m-2 and 161 kW m-2, respectively. Thus, this present work can pave the way to fabricate environmentally friendly fire retardant elastomeric composites for various applications.",
author = "Debdipta Basu and Amit Das and Wang, {De Yi} and George, {Jinu Jacob} and St{\"o}ckelhuber, {Klaus Werner} and Regine Boldt and Andreas Leuteritz and Gert Heinrich",
year = "2016",
doi = "10.1039/c5ra27444c",
language = "English",
volume = "6",
pages = "26425--26436",
journal = "RSC Advances",
issn = "2046-2069",
publisher = "Royal Society of Chemistry",
number = "31",

}

RIS (suitable for import to EndNote) - Lataa

TY - JOUR

T1 - Fire-safe and environmentally friendly nanocomposites based on layered double hydroxides and ethylene propylene diene elastomer

AU - Basu, Debdipta

AU - Das, Amit

AU - Wang, De Yi

AU - George, Jinu Jacob

AU - Stöckelhuber, Klaus Werner

AU - Boldt, Regine

AU - Leuteritz, Andreas

AU - Heinrich, Gert

PY - 2016

Y1 - 2016

N2 - In this work we describe layered double hydroxide (LDH), known as naturally occurring hydrotalcite, based rubber composites that can serve as outstanding fire retardant elastomeric materials. The preparation and detailed characterization of these composites are presented in this study. The inherent slow sulfur cure nature of EPDM rubber is considerably improved by the addition of LDH as realised by the observation of a shortening of the vulcanization time and an improvement of ultimate rheometric torque. This behavior of LDH signifies not only the filler-like character of itself, but also offers vulcanization active surface properties of layered double hydroxide particles. A good rubber-filler interaction was also realised by observing a positive shift of the glass transition temperature of ethylene propylene diene rubber (EPDM) in dynamic mechanical analysis (DMA). The flame retardant property was studied by the cone calorimeter test. The cone calorimeter investigation with sulfur cured gum rubber compounds found a peak heat release rate (PHRR) value of 654 kW m-2. However, at a higher phr loading of Zn-Al LDH i.e., at 40 phr and 100 phr, the PHRR is diminished to 311 kW m-2 and 161 kW m-2, respectively. Thus, this present work can pave the way to fabricate environmentally friendly fire retardant elastomeric composites for various applications.

AB - In this work we describe layered double hydroxide (LDH), known as naturally occurring hydrotalcite, based rubber composites that can serve as outstanding fire retardant elastomeric materials. The preparation and detailed characterization of these composites are presented in this study. The inherent slow sulfur cure nature of EPDM rubber is considerably improved by the addition of LDH as realised by the observation of a shortening of the vulcanization time and an improvement of ultimate rheometric torque. This behavior of LDH signifies not only the filler-like character of itself, but also offers vulcanization active surface properties of layered double hydroxide particles. A good rubber-filler interaction was also realised by observing a positive shift of the glass transition temperature of ethylene propylene diene rubber (EPDM) in dynamic mechanical analysis (DMA). The flame retardant property was studied by the cone calorimeter test. The cone calorimeter investigation with sulfur cured gum rubber compounds found a peak heat release rate (PHRR) value of 654 kW m-2. However, at a higher phr loading of Zn-Al LDH i.e., at 40 phr and 100 phr, the PHRR is diminished to 311 kW m-2 and 161 kW m-2, respectively. Thus, this present work can pave the way to fabricate environmentally friendly fire retardant elastomeric composites for various applications.

U2 - 10.1039/c5ra27444c

DO - 10.1039/c5ra27444c

M3 - Article

VL - 6

SP - 26425

EP - 26436

JO - RSC Advances

JF - RSC Advances

SN - 2046-2069

IS - 31

ER -