TUTCRIS - Tampereen teknillinen yliopisto

TUTCRIS

Preparation of zinc oxide free, transparent rubber nanocomposites using a layered double hydroxide filler

Tutkimustuotosvertaisarvioitu

Yksityiskohdat

AlkuperäiskieliEnglanti
Sivut7194-7200
Sivumäärä7
JulkaisuJournal of Materials Chemistry
Vuosikerta21
Numero20
DOI - pysyväislinkit
TilaJulkaistu - 28 toukokuuta 2011
OKM-julkaisutyyppiA1 Alkuperäisartikkeli

Tiivistelmä

A layered double hydroxide (LDH) mineral filler particle has been designed and employed in rubber vulcanization to prepare a more environmentally friendly rubber composite. The LDH delivers zinc ions in the vulcanization process as accelerators, stearate anions as activators and simultaneously the mineral sheets act as a nanofiller to reinforce the rubber matrix whilst totally replacing the separate zinc oxide (ZnO) and stearic acid conventionally used in the formulation of rubber. This method leads to a significant reduction (nearly 10 times) of the zinc level and yields excellent transparent properties in the final rubber product. The morphological characterization, rheometric curing behaviour, mechanical properties and uniaxial multi-hysteresis behaviours of the resultant rubber/LDH nanocomposite are studied in this paper.

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