Starch-poly(vinyl alcohol) barrier coatings for flexible packaging paper and their effects of phase interactions
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Starch-poly(vinyl alcohol) barrier coatings for flexible packaging paper and their effects of phase interactions. / Christophliemk, Hanna; Ullsten, Henrik; Johansson, Caisa; Järnström, Lars.
julkaisussa: Progress in Organic Coatings, Vuosikerta 111, 01.10.2017, s. 13-22.Tutkimustuotos › › vertaisarvioitu
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TY - JOUR
T1 - Starch-poly(vinyl alcohol) barrier coatings for flexible packaging paper and their effects of phase interactions
AU - Christophliemk, Hanna
AU - Ullsten, Henrik
AU - Johansson, Caisa
AU - Järnström, Lars
PY - 2017/10/1
Y1 - 2017/10/1
N2 - Starch and poly(vinyl alcohol) based barrier coatings for flexible packaging papers were studied. Both octenyl succinate modified and hydroxypropylated corn and potato starches were blended with regular and ethylene modified poly(vinyl alcohol) to increase the water vapor barrier properties and enhance the flexibility of the starch coatings, in order to accomplish superior barrier performance. Phase separation between starch and poly(vinyl alcohol) was studied in detail, both in the solution and in dry draw-down coatings on paper. The barrier performance of the coated paper was evaluated with respect to water vapor transmission rate. Conditions for the creation of a thin surface layer consisting of only one of the pure polymers were identified and discussed in terms of phase separation in solution migration of poly(vinyl alcohol) to the uppermost surface layer. The phase separation promoted low water vapor transmission rates also with a rather high fraction of starch in the coatings.
AB - Starch and poly(vinyl alcohol) based barrier coatings for flexible packaging papers were studied. Both octenyl succinate modified and hydroxypropylated corn and potato starches were blended with regular and ethylene modified poly(vinyl alcohol) to increase the water vapor barrier properties and enhance the flexibility of the starch coatings, in order to accomplish superior barrier performance. Phase separation between starch and poly(vinyl alcohol) was studied in detail, both in the solution and in dry draw-down coatings on paper. The barrier performance of the coated paper was evaluated with respect to water vapor transmission rate. Conditions for the creation of a thin surface layer consisting of only one of the pure polymers were identified and discussed in terms of phase separation in solution migration of poly(vinyl alcohol) to the uppermost surface layer. The phase separation promoted low water vapor transmission rates also with a rather high fraction of starch in the coatings.
KW - Barrier coating
KW - PVOH
KW - Starch
KW - Turbidity
KW - Viscosity
KW - WVTR
KW - XPS
UR - http://www.scopus.com/inward/record.url?scp=85019450052&partnerID=8YFLogxK
U2 - 10.1016/j.porgcoat.2017.04.018
DO - 10.1016/j.porgcoat.2017.04.018
M3 - Article
VL - 111
SP - 13
EP - 22
JO - Progress in Organic Coatings
JF - Progress in Organic Coatings
SN - 0300-9440
ER -