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Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex

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Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex. / Lahbib, Ikram; Valkonen, Arto; Rzaigui, Mohamed; Smirani, Wajda.

julkaisussa: Journal of Cluster Science, Vuosikerta 28, Nro 4, 2017, s. 2239–2252.

Tutkimustuotosvertaisarvioitu

Harvard

Lahbib, I, Valkonen, A, Rzaigui, M & Smirani, W 2017, 'Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex', Journal of Cluster Science, Vuosikerta. 28, Nro 4, Sivut 2239–2252. https://doi.org/10.1007/s10876-017-1217-x

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Author

Lahbib, Ikram ; Valkonen, Arto ; Rzaigui, Mohamed ; Smirani, Wajda. / Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex. Julkaisussa: Journal of Cluster Science. 2017 ; Vuosikerta 28, Nro 4. Sivut 2239–2252.

Bibtex - Lataa

@article{31abeb5db03e448a9b62fb0ab6abc94e,
title = "Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex",
abstract = "A new organic–inorganic hybrid material of formula (C10H15N2)7 Sb2Cl10 Sb2Cl9 (SbCl5)2 SbCl4 2Cl·7H2O was synthesized and characterized by an X-ray diffraction analysis. It crystallizes in the triclinic system with the P(Formula presented.) space group and the following unit cell parameters a = 11.8127(3) {\AA}, b = 15.7557(4) {\AA}, c = 35.4511(8) {\AA}, α = 89.409(1)°, β = 84.04(1)°, γ = 71.116(1)°, Z = 2 and V = 6207.3(3) {\AA}3. The examination of the structure shows that the two dimensional frameworks are produced by O–H Cl, N–H⋯Cl and N–H⋯O hydrogen bonding. In addition, the most important features of crystal packing and intermolecular interactions in the title complex were quantified via Hirshfeld surface analysis. Differential scanning calorimetry has revealed a dehydration phenomenon at around 348 K. The investigation of the antioxidant activity of the title compound was carried out using the 2,2-diphenyl-1-picrylhydrazyl and ferrous iron chelating methods.",
keywords = "Antimonates, Antioxidant activity, Crystal structure, Hirshfeld surface, Photoluminescence",
author = "Ikram Lahbib and Arto Valkonen and Mohamed Rzaigui and Wajda Smirani",
year = "2017",
doi = "10.1007/s10876-017-1217-x",
language = "English",
volume = "28",
pages = "2239–2252",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer Verlag",
number = "4",

}

RIS (suitable for import to EndNote) - Lataa

TY - JOUR

T1 - Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex

AU - Lahbib, Ikram

AU - Valkonen, Arto

AU - Rzaigui, Mohamed

AU - Smirani, Wajda

PY - 2017

Y1 - 2017

N2 - A new organic–inorganic hybrid material of formula (C10H15N2)7 Sb2Cl10 Sb2Cl9 (SbCl5)2 SbCl4 2Cl·7H2O was synthesized and characterized by an X-ray diffraction analysis. It crystallizes in the triclinic system with the P(Formula presented.) space group and the following unit cell parameters a = 11.8127(3) Å, b = 15.7557(4) Å, c = 35.4511(8) Å, α = 89.409(1)°, β = 84.04(1)°, γ = 71.116(1)°, Z = 2 and V = 6207.3(3) Å3. The examination of the structure shows that the two dimensional frameworks are produced by O–H Cl, N–H⋯Cl and N–H⋯O hydrogen bonding. In addition, the most important features of crystal packing and intermolecular interactions in the title complex were quantified via Hirshfeld surface analysis. Differential scanning calorimetry has revealed a dehydration phenomenon at around 348 K. The investigation of the antioxidant activity of the title compound was carried out using the 2,2-diphenyl-1-picrylhydrazyl and ferrous iron chelating methods.

AB - A new organic–inorganic hybrid material of formula (C10H15N2)7 Sb2Cl10 Sb2Cl9 (SbCl5)2 SbCl4 2Cl·7H2O was synthesized and characterized by an X-ray diffraction analysis. It crystallizes in the triclinic system with the P(Formula presented.) space group and the following unit cell parameters a = 11.8127(3) Å, b = 15.7557(4) Å, c = 35.4511(8) Å, α = 89.409(1)°, β = 84.04(1)°, γ = 71.116(1)°, Z = 2 and V = 6207.3(3) Å3. The examination of the structure shows that the two dimensional frameworks are produced by O–H Cl, N–H⋯Cl and N–H⋯O hydrogen bonding. In addition, the most important features of crystal packing and intermolecular interactions in the title complex were quantified via Hirshfeld surface analysis. Differential scanning calorimetry has revealed a dehydration phenomenon at around 348 K. The investigation of the antioxidant activity of the title compound was carried out using the 2,2-diphenyl-1-picrylhydrazyl and ferrous iron chelating methods.

KW - Antimonates

KW - Antioxidant activity

KW - Crystal structure

KW - Hirshfeld surface

KW - Photoluminescence

U2 - 10.1007/s10876-017-1217-x

DO - 10.1007/s10876-017-1217-x

M3 - Article

VL - 28

SP - 2239

EP - 2252

JO - Journal of Cluster Science

JF - Journal of Cluster Science

SN - 1040-7278

IS - 4

ER -