The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate: Conventional versus microwave heating
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The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate : Conventional versus microwave heating. / Dressen, Mark H C L; Stumpel, Jelle E.; Van De Kruijs, Bastiaan H P; Meuldijk, Jan; Vekemans, Jef A J M; Hulshof, Lumbertus A.
julkaisussa: Green Chemistry, Vuosikerta 11, Nro 1, 2009, s. 60-64.Tutkimustuotos › › vertaisarvioitu
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TY - JOUR
T1 - The mechanism of the oxidation of benzyl alcohol by iron(III)nitrate
T2 - Conventional versus microwave heating
AU - Dressen, Mark H C L
AU - Stumpel, Jelle E.
AU - Van De Kruijs, Bastiaan H P
AU - Meuldijk, Jan
AU - Vekemans, Jef A J M
AU - Hulshof, Lumbertus A.
N1 - EXT="Stumpel, Jelle"
PY - 2009
Y1 - 2009
N2 - The mechanism of the oxidation of benzyl alcohol with iron(III)nitrate nonahydrate under conventional and under microwave heating conditions has been investigated and the reaction conditions have been optimized. A series of redox reactions leads to the formation of benzaldehyde and other products. Direct comparison between conventional and microwave heating revealed identical conversions profiles. Mastering the microwave induced heat, absence of a real microwave effect and byproduct formation are the major factors to advise a traditional batch-wise way of process development to a larger scale.
AB - The mechanism of the oxidation of benzyl alcohol with iron(III)nitrate nonahydrate under conventional and under microwave heating conditions has been investigated and the reaction conditions have been optimized. A series of redox reactions leads to the formation of benzaldehyde and other products. Direct comparison between conventional and microwave heating revealed identical conversions profiles. Mastering the microwave induced heat, absence of a real microwave effect and byproduct formation are the major factors to advise a traditional batch-wise way of process development to a larger scale.
UR - http://www.scopus.com/inward/record.url?scp=58149280111&partnerID=8YFLogxK
U2 - 10.1039/b813030b
DO - 10.1039/b813030b
M3 - Article
VL - 11
SP - 60
EP - 64
JO - Green Chemistry
JF - Green Chemistry
SN - 1463-9262
IS - 1
ER -