UV-Blocking Synthetic Biopolymer from Biomass-Based Bifuran Diester and Ethylene Glycol

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UV-Blocking Synthetic Biopolymer from Biomass-Based Bifuran Diester and Ethylene Glycol. / Kainulainen, Tuomo P.; Sirviö, Juho A.; Sethi, Jatin; Hukka, Terttu I.; Heiskanen, Juha P.

julkaisussa: Macromolecules, Vuosikerta 51, Nro 5, 21.02.2018, s. 1822-1829.

Tutkimustuotos › › vertaisarvioitu

Author

Kainulainen, Tuomo P. ; Sirviö, Juho A. ; Sethi, Jatin ; Hukka, Terttu I. ; Heiskanen, Juha P. / UV-Blocking Synthetic Biopolymer from Biomass-Based Bifuran Diester and Ethylene Glycol. Julkaisussa: Macromolecules. 2018 ; Vuosikerta 51, Nro 5. Sivut 1822-1829.

Bibtex - Lataa

@article{a88696658a91406089f5389956dcfa20,

title = "UV-Blocking Synthetic Biopolymer from Biomass-Based Bifuran Diester and Ethylene Glycol",

abstract = "A furan-based synthetic biopolymer composed of a bifuran monomer and ethylene glycol was synthesized through melt polycondensation, and the resulting polyester was found to have promising thermal and mechanical properties. The bifuran monomer, dimethyl 2,2′-bifuran-5,5′-dicarboxylate, was prepared using a palladium-catalyzed, phosphine ligand-free direct coupling protocol. A titanium-catalyzed polycondensation procedure was found effective at polymerizing the bifuran monomer with ethylene glycol. The prepared bifuran polyester exhibited several intriguing properties including high tensile modulus. In addition, the bifuran monomer furnished the polyester with a relatively high glass transition temperature. Films prepared from the new polyester also had excellent oxygen and water barrier properties, which were found to be superior to those of poly(ethylene terephthalate). Moreover, the novel polyester also has good ultraviolet radiation blocking properties.",

keywords = "Biopolymers, Synthesis, Characterization, Thermal analysis, Spectroscopy",

author = "Kainulainen, {Tuomo P.} and Sirvi{\"o}, {Juho A.} and Jatin Sethi and Hukka, {Terttu I.} and Heiskanen, {Juha P.}",

year = "2018",

month = "2",

day = "21",

doi = "10.1021/acs.macromol.7b02457",

language = "English",

volume = "51",

pages = "1822--1829",

journal = "Macromolecules",

issn = "0024-9297",

publisher = "American Chemical Society",

number = "5",

}

RIS (suitable for import to EndNote) - Lataa

TY - JOUR

T1 - UV-Blocking Synthetic Biopolymer from Biomass-Based Bifuran Diester and Ethylene Glycol

AU - Kainulainen, Tuomo P.

AU - Sirviö, Juho A.

AU - Sethi, Jatin

AU - Hukka, Terttu I.

AU - Heiskanen, Juha P.

PY - 2018/2/21

Y1 - 2018/2/21

N2 - A furan-based synthetic biopolymer composed of a bifuran monomer and ethylene glycol was synthesized through melt polycondensation, and the resulting polyester was found to have promising thermal and mechanical properties. The bifuran monomer, dimethyl 2,2′-bifuran-5,5′-dicarboxylate, was prepared using a palladium-catalyzed, phosphine ligand-free direct coupling protocol. A titanium-catalyzed polycondensation procedure was found effective at polymerizing the bifuran monomer with ethylene glycol. The prepared bifuran polyester exhibited several intriguing properties including high tensile modulus. In addition, the bifuran monomer furnished the polyester with a relatively high glass transition temperature. Films prepared from the new polyester also had excellent oxygen and water barrier properties, which were found to be superior to those of poly(ethylene terephthalate). Moreover, the novel polyester also has good ultraviolet radiation blocking properties.

AB - A furan-based synthetic biopolymer composed of a bifuran monomer and ethylene glycol was synthesized through melt polycondensation, and the resulting polyester was found to have promising thermal and mechanical properties. The bifuran monomer, dimethyl 2,2′-bifuran-5,5′-dicarboxylate, was prepared using a palladium-catalyzed, phosphine ligand-free direct coupling protocol. A titanium-catalyzed polycondensation procedure was found effective at polymerizing the bifuran monomer with ethylene glycol. The prepared bifuran polyester exhibited several intriguing properties including high tensile modulus. In addition, the bifuran monomer furnished the polyester with a relatively high glass transition temperature. Films prepared from the new polyester also had excellent oxygen and water barrier properties, which were found to be superior to those of poly(ethylene terephthalate). Moreover, the novel polyester also has good ultraviolet radiation blocking properties.

KW - Biopolymers

KW - Synthesis

KW - Characterization

KW - Thermal analysis

KW - Spectroscopy

U2 - 10.1021/acs.macromol.7b02457

DO - 10.1021/acs.macromol.7b02457

M3 - Article

VL - 51

SP - 1822

EP - 1829

JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 5

ER -

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